Skip to main content
Springer Nature Link
Log in

Technetium as a dehydrogenatton catalyst for alcohols and hydrocarbons

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.
    See More

    The catalytic activity of technetium supported on various carriers has been investigated in the dehydrogenation of aliphatic alcohols and cyclohexane and its derivatives. The most active catalysts were obtained by adding technetium to γ aluminum oxide and rareearth oxides.

  2. 2.

    The specific catalytic activity of technetium on alumina and technetium on yttria catalysts was determined.

  3. 3.

    On the basis of physicochemical investigation of the active surface of the technetium catalysts, assumptions were made concerning the state of technetium on the support surface. The formation of ionic technetium alongside the metallic form was established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Explore related subjects

Discover the latest articles and news from researchers in related subjects, suggested using machine learning.

Literature cited

  1. H. Kubicka, J. Catal.,12, 223 (1968).

    Google Scholar 

  2. A. U. Blackham and J. L. Palmer, U.S. Patent 3,869,333 (1975).

  3. R. L. Mitsche, U.S. Patent 3,574,092 (1969).

  4. A. L. Hensley and T. D. Nevitt, U.S. Patent 3,846,342 (1969).

    Google Scholar 

  5. V. I. Spitsyn, G. N. Pirogova, A. F. Kuzina, G. E. Kalinina, T. A. Lagutina, and A. A. Oblova, Dokl. Akad. Nauk SSSR,246, 126 (1979).

    Google Scholar 

  6. G. K. Boreskov and A. P. Karnaukhov, Zh. Fiz. Khim.,26, 814 (1952).

    Google Scholar 

  7. N. E. Buyanova and A. P. Karnaukhov, in: Mechanism and Kinetics of Catalytic Processes [in Russian], Nauka, Novosibirsk (1977), p. 1965.

    Google Scholar 

  8. P. A. Serman and G. C. Bond, J. Chem. Soc. Faraday Trans. 1,76, 889 (1980).

    Google Scholar 

  9. A. K. Lavrukhina and A. A. Pozdnyakov, The Analytical Chemistry of Technetium, Promethium, Astatine, and Francium [in Russian], Nauka, Moscow (1966), p. 28.

    Google Scholar 

  10. O. Müller, W. White, and R. Roy, J. Inorg. Nucl. Chem.,26, 2075 (1964).

    Google Scholar 

  11. Z. V. Luk'yanova, V. I. Shekhovalova, and V. S. Voronin, Vestn. Mosk Univ., No. 3, 63 (1978).

    Google Scholar 

  12. V. I. Spitsyn, G. N. Pirogova, and R. I. Korostoleva, Dokl. Akad. Nauk SSSR,208, 878 (1973).

    Google Scholar 

  13. V. I. Spitsyn, G. N. Pirogova, R. I. Korosteleva, and T. A. Lagutina, Izv. Akad. Nauk SSSR, Ser. Khim., 1906 (1978).

  14. A. Vinke and E. Petersen, Kinet. Katal.,18, 561 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Instiute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    G. N. Pirogova, N. M. Prokhorets, T. A. Lagutina & R. I. Korosteleva

Authors
  1. G. N. Pirogova
    View author publications

    You can also search for this author inPubMed Google Scholar

  2. N. M. Prokhorets
    View author publications

    You can also search for this author inPubMed Google Scholar

  3. T. A. Lagutina
    View author publications

    You can also search for this author inPubMed Google Scholar

  4. R. I. Korosteleva
    View author publications

    You can also search for this author inPubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 850–855, April, 1982.

The authors thank A. E. Chalykh and V. V. Matveev for the electron-microscope studies.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pirogova, G.N., Prokhorets, N.M., Lagutina, T.A. et al. Technetium as a dehydrogenatton catalyst for alcohols and hydrocarbons. Russ Chem Bull 31, 747–751 (1982). https://doi.org/10.1007/BF00950011

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950011

Keywords